ETHYL BETA-APO-8'-CAROTENOATE (TRANS)

Base Information

  • Chemical Name: ETHYL BETA-APO-8'-CAROTENOATE (TRANS)
  • CAS No.: 1109-11-1

Reputable manufacturer supply ETHYL BETA-APO-8'-CAROTENOATE (TRANS) 1109-11-1 in stock with high standard

  • Molecular Formula: C32H44 O2
  • Molecular Weight: 460.7
  • Melting Point: 134-136 °C 
  • Boiling Point: 589.5°Cat760mmHg 
  • Flash Point: 338.3°C 
  • PSA: 26.30000 
  • Density: 0.963g/cm3 
  • LogP: 9.08610 

1109-11-1 Relevant articles

Carotenoid syntheses via sulfones. Synthesis of apocarotenoids and torularhodin ethyl ester

Fischli,Mayer

, p. 1492 - 1497 (2007/10/12)

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1109-11-1 Process route

(E)-3-methylpent-2-en-4-yn-1-ol
6153-06-6,105-29-3

(E)-3-methylpent-2-en-4-yn-1-ol

trans-apo-8'-carotenic acid ethyl ester
1109-11-1

trans-apo-8'-carotenic acid ethyl ester

Conditions
Conditions Yield
Multi-step reaction with 6 steps
1: (i) EtMgBr, (ii) /BRN= 605384/
2: H2 , pyridin-3-yl-methanol / Lindlar catalyst / ethanol; petroleum ether
3: aq. HCl / diethyl ether
4: NaOEt / benzene / 5 h / 5 °C
5: MnO2 / diethyl ether
6: (i) NaOEt, (ii) I2
With 3-hydroxymethylpyridin; hydrogenchloride; manganese(IV) oxide; hydrogen; sodium ethanolate; Lindlar's catalyst; In diethyl ether; ethanol; Petroleum ether; benzene;
(<i>E</i>)-6,6-diethoxy-3-methyl-hex-2-en-4-yn-1-ol
1069-94-9

(E )-6,6-diethoxy-3-methyl-hex-2-en-4-yn-1-ol

trans-apo-8'-carotenic acid ethyl ester
1109-11-1

trans-apo-8'-carotenic acid ethyl ester

Conditions
Conditions Yield
Multi-step reaction with 5 steps
1: H2 , pyridin-3-yl-methanol / Lindlar catalyst / ethanol; petroleum ether
2: aq. HCl / diethyl ether
3: NaOEt / benzene / 5 h / 5 °C
4: MnO2 / diethyl ether
5: (i) NaOEt, (ii) I2
With 3-hydroxymethylpyridin; hydrogenchloride; manganese(IV) oxide; hydrogen; sodium ethanolate; Lindlar's catalyst; In diethyl ether; ethanol; Petroleum ether; benzene;

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